ARgh! Am I ever a bozo. I even went and ordered connectors! Somehow I never comprehended until now while staring at the picture above that this "mezzanine slot" was 140 pins, while the original was 160 pins. The existing pinout is genuinely worthless for reverse engineering this. What a maroon. I don't have the chops to reverse engineer a pinout from scratch without a higher end logic analyzer than my poor old HP 16500C. Even then, I'd be limited to blindly probing until I found address lines on a running iMac. Yikes.
None of the surrounding chips can be beeped out either, since I don't have any pinouts for them.
Without a schematic there is absolutely no way I'm capable of making this slot actually do anything, so I don't suppose y'all have any slot loading iMac schematics lying around, do you?
Edit: I might be able to borrow the Firewire daughterboard from an early iMac DV and use the firewire chip (publicly available, TI TSB12LV23) to map out the pin assignments on its header, so this isn't a complete wash. I want my PCI iMac G3